Mechanistic Studies on Trichoacorenol Synthase from Amycolatopsis benzoatilytica

Isotopic labeling experiments performed with a newly identified bacterial trichoacorenol synthase established a 1,5‐hydride shift occurring in the cyclization mechanism. During EI‐MS analysis, major fragments of the sesquiterpenoid were shown to arise via cryptic hydrogen movements. Therefore, the i...

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Detalles Bibliográficos
Autores principales: Rinkel, Jan, Dickschat, Jeroen S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155024/
https://www.ncbi.nlm.nih.gov/pubmed/31553510
http://dx.doi.org/10.1002/cbic.201900584

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155024/
https://www.ncbi.nlm.nih.gov/pubmed/31553510
http://dx.doi.org/10.1002/cbic.201900584

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