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Electrophotocatalytic Undirected C−H Trifluoromethylations of (Het)Arenes

Electrophotochemistry has enabled arene C−H trifluoromethylation with the Langlois reagent CF(3)SO(2)Na under mild reaction conditions. The merger of electrosynthesis and photoredox catalysis provided a chemical oxidant‐free approach for the generation of the CF(3) radical. The electrophotochemistry...

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Detalles Bibliográficos
Autores principales: Qiu, Youai, Scheremetjew, Alexej, Finger, Lars H., Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155051/
https://www.ncbi.nlm.nih.gov/pubmed/31875327
http://dx.doi.org/10.1002/chem.201905774