Cargando…

Electrophotocatalytic Undirected C−H Trifluoromethylations of (Het)Arenes

Electrophotochemistry has enabled arene C−H trifluoromethylation with the Langlois reagent CF(3)SO(2)Na under mild reaction conditions. The merger of electrosynthesis and photoredox catalysis provided a chemical oxidant‐free approach for the generation of the CF(3) radical. The electrophotochemistry...

Descripción completa

Detalles Bibliográficos
Autores principales:	Qiu, Youai, Scheremetjew, Alexej, Finger, Lars H., Ackermann, Lutz
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155051/ https://www.ncbi.nlm.nih.gov/pubmed/31875327 http://dx.doi.org/10.1002/chem.201905774

Ejemplares similares

Radical C−H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide
por: Dix, Stefan, et al.
Publicado: (2021)

Chemo‐ and Site‐Selective Electro‐Oxidative Alkane Fluorination by C(sp(3))−H Cleavage
por: Stangier, Maximilian, et al.
Publicado: (2022)

Olefination of carbonyls with alkenes enabled by electrophotocatalytic generation of distonic radical cations
por: Steiniger, Keri A., et al.
Publicado: (2023)

Electrooxidative palladium- and enantioselective rhodium-catalyzed [3 + 2] spiroannulations
por: Wei, Wen, et al.
Publicado: (2022)

Electrochemical B−H Nitrogenation: Access to Amino Acid and BODIPY‐Labeled nido‐Carboranes
por: Yang, Long, et al.
Publicado: (2020)

Azaruthena(II)‐bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)‐catalyzed Alkyne Annulations
por: Yang, Long, et al.
Publicado: (2020)

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities
por: Hartwig, John F., et al.
Publicado: (2016)

Undirected C-H Bond Activation in Aluminium Hydrido Enaminonates
por: Amadi, Chijioke Kingsley, et al.
Publicado: (2023)

Catalytic Undirected Meta‐Selective C–H Borylation of Metallocenes
por: Zheng, Hao, et al.
Publicado: (2023)

Catalytic activation of a single C–F bond in trifluoromethyl arenes
por: Dang, Hester, et al.
Publicado: (2016)

C−H Fluoromethoxylation of Arenes by Photoredox Catalysis
por: Bertoli, Giulia, et al.
Publicado: (2022)

Direct C−H Trifluoromethylation of (Hetero)Arenes in Water Enabled by Organic Photoredox‐Active Amphiphilic Nanoparticles
por: Eisenreich, Fabian, et al.
Publicado: (2022)

Trifluoromethyl Sulfoxides: Reagents for Metal‐Free C−H Trifluoromethylthiolation
por: Wang, Dong, et al.
Publicado: (2020)

Nanostructured Carbon Nitride for Continuous-Flow Trifluoromethylation of (Hetero)arenes
por: Sivo, Alessandra, et al.
Publicado: (2023)

One‐Pot C−H Functionalization of Arenes by Diaryliodonium Salts
por: Reitti, Marcus, et al.
Publicado: (2016)

Recent Progress in the Synthesis of Drugs and Bioactive Molecules Incorporating Nitro(het)arene Core
por: Bastrakov, Maxim, et al.
Publicado: (2022)

Electrochemical C−H Functionalization of (Hetero)Arenes—Optimized by DoE
por: Dörr, Maurice, et al.
Publicado: (2020)

Catalytic C–H Trifluoromethylation of Arenes and Heteroarenes via Visible Light Photoexcitation of a Co(III)–CF(3) Complex
por: Kuehner, Christopher S., et al.
Publicado: (2023)

Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
por: Yang, Long, et al.
Publicado: (2021)

New Cysteine Protease Inhibitors: Electrophilic (Het)arenes and Unexpected Prodrug Identification for the Trypanosoma Protease Rhodesain
por: Klein, Philipp, et al.
Publicado: (2020)

Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
por: Li, Jie, et al.
Publicado: (2017)

Site‐Selective C−H Arylation of Diverse Arenes Ortho to Small Alkyl Groups
por: Dhankhar, Jyoti, et al.
Publicado: (2022)

The Mechanism of Toxicity in HET-S/HET-s Prion Incompatibility
por: Seuring, Carolin, et al.
Publicado: (2012)

Rhodium‐Catalyzed Electrooxidative C−H Olefination of Benzamides
por: Zhang, Yan, et al.
Publicado: (2020)

Synthesis of C‐Oligosaccharides through Versatile C(sp(3))−H Glycosylation of Glycosides
por: Wu, Jun, et al.
Publicado: (2022)

Iron‐Catalyzed Intramolecular Arene C(sp(2))−H Amidations under Mechanochemical Conditions
por: Shi, Peng, et al.
Publicado: (2022)

Amplification on Undirected Population Structures: Comets Beat Stars
por: Pavlogiannis, Andreas, et al.
Publicado: (2017)

Efficient solution for finding Hamilton cycles in undirected graphs
por: Alhalabi, Wadee, et al.
Publicado: (2016)

Infinite Ergodic Walks in Finite Connected Undirected Graphs †
por: Volchenkov, Dimitri
Publicado: (2021)

Mechanism of the Arene‐Limited Nondirected C−H Activation of Arenes with Palladium
por: Wedi, Philipp, et al.
Publicado: (2021)

Nickela‐electrocatalyzed Mild C−H Alkylations at Room Temperature
por: Samanta, Ramesh C., et al.
Publicado: (2020)

Dehydroepiandrosterone (DHEA) increases undirected singing behavior and alters dopaminergic regulation of undirected song in non-breeding male European starlings (Sturnus vulgaris)
por: Heimovics, Sarah, et al.
Publicado: (2023)

Electrochemical Access to Aza‐Polycyclic Aromatic Hydrocarbons: Rhoda‐Electrocatalyzed Domino Alkyne Annulations
por: Kong, Wei‐Jun, et al.
Publicado: (2020)

Synthesis of (Het)aryl 2-(2-hydroxyaryl)cyclopropyl Ketones
por: Fadeev, Alexander A., et al.
Publicado: (2020)

Electrochemical C−H Amidation of Heteroarenes with N‐Alkyl Sulfonamides in Aqueous Medium
por: Zhang, Yan, et al.
Publicado: (2020)

One pot synthesis of trifluoromethyl aryl sulfoxides by trifluoromethylthiolation of arenes and subsequent oxidation with hydrogen peroxide
por: Horvat, Monika, et al.
Publicado: (2020)

Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
por: Lin, Jin, et al.
Publicado: (2017)

Arene C−H Activation at Aluminium(I): meta Selectivity Driven by the Electronics of S(N)Ar Chemistry
por: Hicks, Jamie, et al.
Publicado: (2020)

Photochemical C(sp (2))−H Pyridination via Arene–Pyridinium Electron Donor–Acceptor Complexes
por: Lasky, Matthew R., et al.
Publicado: (2022)

Photoelectrocatalytic Arene C-H Amination
por: Zhang, Lei, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_tfspoi0lo8ptb5u13drcbio80o