Radical C−N Borylation of Aromatic Amines Enabled by a Pyrylium Reagent

Herein, we report a radical borylation of aromatic amines through a homolytic C(sp(2))−N bond cleavage. This method capitalizes on a simple and mild activation via a pyrylium reagent ((Sc)Pyry‐OTf) thus priming the amino group for reactivity. The combination of terpyridine and a diboron reagent trig...

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Detalles Bibliográficos
Autores principales: Ma, Yuanhong, Pang, Yue, Chabbra, Sonia, Reijerse, Edward J., Schnegg, Alexander, Niski, Jan, Leutzsch, Markus, Cornella, Josep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155052/
https://www.ncbi.nlm.nih.gov/pubmed/31994764
http://dx.doi.org/10.1002/chem.202000412

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155052/
https://www.ncbi.nlm.nih.gov/pubmed/31994764
http://dx.doi.org/10.1002/chem.202000412

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