Effective and Reversible Carbon Dioxide Insertion into Cerium Pyrazolates

The homoleptic pyrazolate complexes [Ce(III) (4)(Me(2)pz)(12)] and [Ce(IV)(Me(2)pz)(4)](2) quantitatively insert CO(2) to give [Ce(III) (4)(Me(2)pz⋅CO(2))(12)] and [Ce(IV)(Me(2)pz⋅CO(2))(4)], respectively (Me(2)pz=3,5‐dimethylpyrazolato). This process is reversible for both complexes, as observed by...

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Detalles Bibliográficos
Autores principales: Bayer, Uwe, Werner, Daniel, Maichle‐Mössmer, Cäcilia, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155069/
https://www.ncbi.nlm.nih.gov/pubmed/31916355
http://dx.doi.org/10.1002/anie.201916483

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155069/
https://www.ncbi.nlm.nih.gov/pubmed/31916355
http://dx.doi.org/10.1002/anie.201916483

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