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Electrochemical‐Induced Ring Transformation of Cyclic α‐(ortho‐Iodophenyl)‐β‐oxoesters
Cyclic α‐(ortho‐iodophenyl)‐β‐oxoesters were converted in a ring‐expanding transformation to furnish benzannulated cycloalkanone carboxylic esters. The reaction sequence started by electrochemical reduction of the iodoarene moiety. In a mechanistic rationale, the resulting carbanionic species was ad...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155071/ https://www.ncbi.nlm.nih.gov/pubmed/31850604 http://dx.doi.org/10.1002/chem.201905570 |