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Synthesis of 1,4,6-Tricarbonyl Compounds via Regioselective Gold(I)-Catalyzed Alkyne Hydration and Their Application in the Synthesis of α-Arylidene-butyrolactones
[Image: see text] We report a direct, straightforward, and regioselective hydration of 1,4-enynes designed from Morita–Baylis–Hillman adducts. Under smooth conditions and short reaction times, gold-catalyzed hydration of internal alkynes provides synthetically useful ketones as single regioisomers i...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7161055/ https://www.ncbi.nlm.nih.gov/pubmed/32309713 http://dx.doi.org/10.1021/acsomega.0c00101 |