Design of Ru(II)-NHC-Diamine Precatalysts Directed by Ligand Cooperation: Applications and Mechanistic Investigations for Asymmetric Hydrogenation

[Image: see text] A modular synthesis of Ru(II)-NHC-diamine complexes from readily available chiral N-heterocyclic carbenes (NHCs) and chiral diamines is disclosed for the first time. The well-defined Ru(II)-NHC-diamine complexes show unique structure and coordination chemistry including an unusual...

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Detalles Bibliográficos
Autores principales: Li, Wei, Wagener, Tobias, Hellmann, Lars, Daniliuc, Constantin G., Mück-Lichtenfeld, Christian, Neugebauer, Johannes, Glorius, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7168601/
https://www.ncbi.nlm.nih.gov/pubmed/32195584
http://dx.doi.org/10.1021/jacs.0c00985

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7168601/
https://www.ncbi.nlm.nih.gov/pubmed/32195584
http://dx.doi.org/10.1021/jacs.0c00985

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