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Strong Impact of Intramolecular Hydrogen Bonding on the Cathodic Path of [Re(3,3′-dihydroxy-2,2′-bipyridine)(CO)(3)Cl] and Catalytic Reduction of Carbon Dioxide

[Image: see text] Herein, we present the cathodic paths of the Group-7 metal complex [Re(3,3′-DHBPY)(CO)(3)Cl] (3,3′-DHBPY = 3,3′-dihydroxy-2,2′-bipyridine) producing a moderately active catalyst of electrochemical reduction of CO(2) to CO. The combined techniques of cyclic voltammetry and IR/UV–vis...

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Detalles Bibliográficos
Autores principales: Taylor, James O., Neri, Gaia, Banerji, Liam, Cowan, Alexander J., Hartl, František
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7175459/
https://www.ncbi.nlm.nih.gov/pubmed/32237729
http://dx.doi.org/10.1021/acs.inorgchem.0c00263