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Strong Impact of Intramolecular Hydrogen Bonding on the Cathodic Path of [Re(3,3′-dihydroxy-2,2′-bipyridine)(CO)(3)Cl] and Catalytic Reduction of Carbon Dioxide
[Image: see text] Herein, we present the cathodic paths of the Group-7 metal complex [Re(3,3′-DHBPY)(CO)(3)Cl] (3,3′-DHBPY = 3,3′-dihydroxy-2,2′-bipyridine) producing a moderately active catalyst of electrochemical reduction of CO(2) to CO. The combined techniques of cyclic voltammetry and IR/UV–vis...
Autores principales: | Taylor, James O., Neri, Gaia, Banerji, Liam, Cowan, Alexander J., Hartl, František |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7175459/ https://www.ncbi.nlm.nih.gov/pubmed/32237729 http://dx.doi.org/10.1021/acs.inorgchem.0c00263 |
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