Use of Pyrazole Hydrogen Bonding in Tripodal Complexes to Form Self Assembled Homochiral Dimers

The 3:1 condensation of 5-methyl-1H-pyrazole-3-carboxaldehyde (MepyrzH) with tris(2-aminoethyl)amine (tren) gives the tripodal ligand tren(MePyrzH)(3). Aerial oxidation of a solution of cobalt(II) with this ligand in the presence of base results in the isolation of the insoluble Co(tren)(MePyrz)(3.)...

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Detalles Bibliográficos
Autores principales: Brewer, Greg, Butcher, Raymond J., Zavalij, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178049/
https://www.ncbi.nlm.nih.gov/pubmed/32244503
http://dx.doi.org/10.3390/ma13071595

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178049/
https://www.ncbi.nlm.nih.gov/pubmed/32244503
http://dx.doi.org/10.3390/ma13071595

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