Na–Ni–H Phase Formation at High Pressures and High Temperatures: Hydrido Complexes [NiH(5)](3–)Versus the Perovskite NaNiH(3)

[Image: see text] The Na–Ni–H system was investigated by in situ synchrotron diffraction studies of reaction mixtures NaH–Ni–H(2) at around 5, 10, and 12 GPa. The existence of ternary hydrogen-rich hydrides with compositions Na(3)NiH(5) and NaNiH(3), where Ni attains the oxidation state II, is demon...

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Detalles Bibliográficos
Autores principales: Spektor, Kristina, Crichton, Wilson A., Filippov, Stanislav, Klarbring, Johan, Simak, Sergei I., Fischer, Andreas, Häussermann, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178781/
https://www.ncbi.nlm.nih.gov/pubmed/32337435
http://dx.doi.org/10.1021/acsomega.0c00239

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178781/
https://www.ncbi.nlm.nih.gov/pubmed/32337435
http://dx.doi.org/10.1021/acsomega.0c00239

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