Revealing the Iron-Catalyzed β-Methyl Scission of tert-Butoxyl Radicals via the Mechanistic Studies of Carboazidation of Alkenes

We describe here a mechanistic study of the iron-catalyzed carboazidation of alkenes involving an intriguing metal-assisted β-methyl scission process. Although t-BuO radical has frequently been observed in experiments, the β-methyl scission from a t-BuO radical into a methyl radical and acetone is s...

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Detalles Bibliográficos
Autores principales: Chiou, Mong-Feng, Xiong, Haigen, Li, Yajun, Bao, Hongli, Zhang, Xinhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7179474/
https://www.ncbi.nlm.nih.gov/pubmed/32182775
http://dx.doi.org/10.3390/molecules25051224

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7179474/
https://www.ncbi.nlm.nih.gov/pubmed/32182775
http://dx.doi.org/10.3390/molecules25051224

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