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One-Pot Iridium Catalyzed C–H Borylation/Sonogashira Cross-Coupling: Access to Borylated Aryl Alkynes

Borylated aryl alkynes have been synthesized via one-pot iridium catalyzed C–H borylation (CHB)/Sonogashira cross-coupling of aryl bromides. Direct borylation of aryl alkynes encountered problems related to the reactivity of the alkyne under CHB conditions. However, tolerance of aryl bromides to CHB...

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Detalles Bibliográficos
Autores principales: Chotana, Ghayoor A., Montero Bastidas, Jose R., Miller, Susanne L., Smith, Milton R., Maleczka, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7181282/
https://www.ncbi.nlm.nih.gov/pubmed/32290238
http://dx.doi.org/10.3390/molecules25071754