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Delocalized electron effect on single metal sites in ultrathin conjugated microporous polymer nanosheets for boosting CO(2) cycloaddition
CO(2) cycloaddition with epoxides at low temperature and pressure has been broadly recognized as an ambitious but challenging goal, which requires the catalysts to have precisely controlled Lewis acid sites. Here, we demonstrate that both stereochemical environment and oxidation state of single coba...
Autores principales: | , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Association for the Advancement of Science
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7182427/ https://www.ncbi.nlm.nih.gov/pubmed/32426463 http://dx.doi.org/10.1126/sciadv.aaz4824 |