Mercaptothiacalixarenes Steer 24 Copper(I) Centers to form a Hollow‐Sphere Structure Featuring Cu(2)S(2) Motifs with Exceptionally Short Cu⋅⋅⋅Cu Distances

Tetramercaptotetrathiacalix[4]arene (LH(4)) can be used as a coordination platform to bind four Cu(I) ions at the thiolate and thioether S atoms. Donor ligands such as phosphanes can stabilize the resulting [LCu(4)] units, which then remain monomeric ([(Ph(3)PCu)(4)L]). In the absence of donor ligan...

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Detalles Bibliográficos
Autores principales: Frank, Nicolas, Dallmann, André, Braun‐Cula, Beatrice, Herwig, Christian, Limberg, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187159/
https://www.ncbi.nlm.nih.gov/pubmed/32009289
http://dx.doi.org/10.1002/anie.201915882

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187159/
https://www.ncbi.nlm.nih.gov/pubmed/32009289
http://dx.doi.org/10.1002/anie.201915882

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