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Carbon–Phosphorus Coupling from C^N Cyclometalated Au(III) Complexes

With the aim of exploiting new organometallic species for cross‐coupling reactions, we report here on the Au(III)‐mediated C(aryl)−P bond formation occurring upon reaction of C^N cyclometalated Au(III) complexes with phosphines. The [Au(C^N)Cl(2)] complex 1 featuring the bidentate 2‐benzoylpyridine...

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Detalles Bibliográficos
Autores principales: Bonsignore, Riccardo, Thomas, Sophie R., Klooster, Wim T., Coles, Simon J., Jenkins, Robert L., Bourissou, Didier, Barone, Giampaolo, Casini, Angela
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187188/
https://www.ncbi.nlm.nih.gov/pubmed/31994237
http://dx.doi.org/10.1002/chem.201905392