Iron‐Catalyzed C−H Activation with Propargyl Acetates: Mechanistic Insights into Iron(II) by Experiment, Kinetics, Mössbauer Spectroscopy, and Computation

An iron‐catalyzed C−H/N−H alkyne annulation was realized by using a customizable clickable triazole amide under exceedingly mild reaction conditions. A unifying mechanistic approach combining experiment, spectroscopy, kinetics, and computation provided strong support for facile C−H activation by a l...

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Detalles Bibliográficos
Autores principales: Mo, Jiayu, Müller, Thomas, Oliveira, João C. A., Demeshko, Serhiy, Meyer, Franc, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187192/
https://www.ncbi.nlm.nih.gov/pubmed/31207070
http://dx.doi.org/10.1002/anie.201904110

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187192/
https://www.ncbi.nlm.nih.gov/pubmed/31207070
http://dx.doi.org/10.1002/anie.201904110

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