N,N′‐Ethylene‐Bridged Bis‐2‐Aryl‐Pyrrolinium Cations to E‐Diaminoalkenes: Non‐Identical Stepwise Reversible Double‐Redox Coupled Bond Activation Reactions

This work presents a stepwise reversible two‐electron transfer induced hydrogen shift leading to the conversion of a bis‐pyrrolinium cation to an E‐diaminoalkene and vice versa. Remarkably, the forward and the reverse reaction, which are both reversible, follow two completely different reaction path...

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Detalles Bibliográficos
Autores principales: Nayak, Mithilesh Kumar, Stubbe, Jessica, Neuman, Nicolás I., Narayanan, Ramakirushnan Suriya, Maji, Sandipan, Schulzke, Carola, Chandrasekhar, Vadapalli, Sarkar, Biprajit, Jana, Anukul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187269/
https://www.ncbi.nlm.nih.gov/pubmed/31994763
http://dx.doi.org/10.1002/chem.202000255

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187269/
https://www.ncbi.nlm.nih.gov/pubmed/31994763
http://dx.doi.org/10.1002/chem.202000255

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