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N,N′‐Ethylene‐Bridged Bis‐2‐Aryl‐Pyrrolinium Cations to E‐Diaminoalkenes: Non‐Identical Stepwise Reversible Double‐Redox Coupled Bond Activation Reactions

This work presents a stepwise reversible two‐electron transfer induced hydrogen shift leading to the conversion of a bis‐pyrrolinium cation to an E‐diaminoalkene and vice versa. Remarkably, the forward and the reverse reaction, which are both reversible, follow two completely different reaction path...

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Detalles Bibliográficos
Autores principales:	Nayak, Mithilesh Kumar, Stubbe, Jessica, Neuman, Nicolás I., Narayanan, Ramakirushnan Suriya, Maji, Sandipan, Schulzke, Carola, Chandrasekhar, Vadapalli, Sarkar, Biprajit, Jana, Anukul
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187269/ https://www.ncbi.nlm.nih.gov/pubmed/31994763 http://dx.doi.org/10.1002/chem.202000255

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