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Evaluating the Solvent Stark Effect from Temperature‐Dependent Solvatochromic Shifts of Anthracene
The solvent Stark effect on the spectral shifts of anthracene is studied with temperature‐dependent solvatochromic measurements. The Stark contribution Δv (Stark) to the absorption shift Δv (p) in polar solvents is measured to be Δv (Stark)=(53±35) cm(−1), in reasonable agreement with dielectric con...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187296/ https://www.ncbi.nlm.nih.gov/pubmed/31990122 http://dx.doi.org/10.1002/cphc.202000010 |