Remote Participation during Glycosylation Reactions of Galactose Building Blocks: Direct Evidence from Cryogenic Vibrational Spectroscopy

The stereoselective formation of 1,2‐cis‐glycosidic bonds is challenging. However, 1,2‐cis‐selectivity can be induced by remote participation of C4 or C6 ester groups. Reactions involving remote participation are believed to proceed via a key ionic intermediate, the glycosyl cation. Although mechani...

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Detalles Bibliográficos
Autores principales: Marianski, Mateusz, Mucha, Eike, Greis, Kim, Moon, Sooyeon, Pardo, Alonso, Kirschbaum, Carla, Thomas, Daniel A., Meijer, Gerard, von Helden, Gert, Gilmore, Kerry, Seeberger, Peter H., Pagel, Kevin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187407/
https://www.ncbi.nlm.nih.gov/pubmed/31944510
http://dx.doi.org/10.1002/anie.201916245

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187407/
https://www.ncbi.nlm.nih.gov/pubmed/31944510
http://dx.doi.org/10.1002/anie.201916245

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