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Enantioselective Synthesis of a Tricyclic, sp(3)‐Rich Diazatetradecanedione: an Amino Acid‐Based Natural Product‐Like Scaffold
6‐, 7‐, and 8‐membered rings are assembled from a linear precursor by successive cyclisation reactions to construct a tricyclic diazatricyclo[6.5.1.0(4, 9)]‐tetradecanedione scaffold. Advanced building blocks based on d‐aspartic acid and l‐pyroglutamic acid were combined by a sp(3)−sp(2) Negishi cou...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187416/ https://www.ncbi.nlm.nih.gov/pubmed/31846111 http://dx.doi.org/10.1002/chem.201905144 |