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An Isolable Bis(Silanone–Borane) Adduct
The reaction of bis(silylenyl)‐substituted ferrocene 1 with two molar equivalents of BPh(3) yields the corresponding bis(silylene–borane) Lewis adduct 2. The latter is capable to activate CO(2) to furnish the borane‐stabilized bis(silanone) 3 through mono‐oxygenation of the dative Si(II)→B silicon c...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187440/ https://www.ncbi.nlm.nih.gov/pubmed/32017257 http://dx.doi.org/10.1002/chem.202000235 |