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An Isolable Bis(Silanone–Borane) Adduct

The reaction of bis(silylenyl)‐substituted ferrocene 1 with two molar equivalents of BPh(3) yields the corresponding bis(silylene–borane) Lewis adduct 2. The latter is capable to activate CO(2) to furnish the borane‐stabilized bis(silanone) 3 through mono‐oxygenation of the dative Si(II)→B silicon c...

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Detalles Bibliográficos
Autores principales: Luecke, Marcel‐Philip, Pens, Elron, Yao, Shenglai, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187440/
https://www.ncbi.nlm.nih.gov/pubmed/32017257
http://dx.doi.org/10.1002/chem.202000235