Regio‐ and Stereoselective Synthesis of 1,1‐Diborylalkenes via Brønsted Base‐Catalyzed Mixed Diboration of Alkynyl Esters and Amides with BpinBdan

The NaOtBu‐catalyzed mixed 1,1‐diboration of terminal alkynes using the unsymmetrical diboron reagent BpinBdan (pin = pinacolato; dan = 1,8‐diaminonaphthalene) proceeds in a regio‐ and stereoselective fashion affording moderate to high yields of 1,1‐diborylalkenes bearing orthogonal boron protecting...

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Detalles Bibliográficos
Autores principales: Liu, Xiaocui, Ming, Wenbo, Luo, Xiaoling, Friedrich, Alexandra, Maier, Jan, Radius, Udo, Santos, Webster L., Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187442/
https://www.ncbi.nlm.nih.gov/pubmed/32362780
http://dx.doi.org/10.1002/ejoc.202000128

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187442/
https://www.ncbi.nlm.nih.gov/pubmed/32362780
http://dx.doi.org/10.1002/ejoc.202000128

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