Oxidative Addition of Aryl Halides to a Triphosphine Ni(0) Center to Form Pentacoordinate Ni(II) Aryl Species

[Image: see text] Oxidative addition of aryl halides to Ni(0) is a ubiquitous elementary step in cross-coupling and related reactions, usually producing a square-planar Ni(II)–aryl intermediate. Here we show that a triphosphine ligand supports oxidative addition at a tris-ligated Ni(0) center to cle...

Descripción completa

Detalles Bibliográficos
Autores principales: Pérez−García, Pablo M., Darù, Andrea, Scheerder, Arthur R., Lutz, Martin, Harvey, Jeremy N., Moret, Marc-Etienne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7189616/
https://www.ncbi.nlm.nih.gov/pubmed/32362705
http://dx.doi.org/10.1021/acs.organomet.0c00060

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7189616/
https://www.ncbi.nlm.nih.gov/pubmed/32362705
http://dx.doi.org/10.1021/acs.organomet.0c00060

Ejemplares similares