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Validation of Enthalpy–Entropy Compensation Mechanism in Partial Amide Bond Rotation
[Image: see text] The concept of enthalpy–entropy compensation (EEC) is one of the highly debated areas of thermodynamics. The conformational change due to restricted double-bond rotation shows a classic two-site chemical exchange phenomenon and has been extensively studied. Fifty-four analogs of N,...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7191833/ https://www.ncbi.nlm.nih.gov/pubmed/32363286 http://dx.doi.org/10.1021/acsomega.0c00332 |