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Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores

The correlation between molecular packing structure and its room-temperature phosphorescence (RTP), hence rational promotion of the intensity, remains unclear. We herein present racemism enhanced RTP chiral chromophores by 2,2-bis-(diphenylphosphino)-1,1-napthalene (rac-BINAP) in comparison to its c...

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Detalles Bibliográficos
Autores principales: Wu, Xiugang, Huang, Chun-Ying, Chen, Deng-Gao, Liu, Denghui, Wu, Chichi, Chou, Keh-Jiunh, Zhang, Bin, Wang, Yafei, Liu, Yu, Li, Elise Y., Zhu, Weiguo, Chou, Pi-Tai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7195388/
https://www.ncbi.nlm.nih.gov/pubmed/32358521
http://dx.doi.org/10.1038/s41467-020-15976-5