Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering

Cross-coupling reactions enable rapid, convergent synthesis of diverse molecules and provide the foundation for modern chemical synthesis. The most widely used methods employ sp(2)-hybridized coupling partners, such as aryl halides or related pre-functionalized substrates. Here, we demonstrate coppe...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Huayou, Chen, Si-Jie, Mandal, Mukunda, Pratik, Saied Md, Buss, Joshua A., Krska, Shane W., Cramer, Christopher J., Stahl, Shannon S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7197765/
https://www.ncbi.nlm.nih.gov/pubmed/32368720
http://dx.doi.org/10.1038/s41929-020-0425-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7197765/
https://www.ncbi.nlm.nih.gov/pubmed/32368720
http://dx.doi.org/10.1038/s41929-020-0425-1

Ejemplares similares