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Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering
Cross-coupling reactions enable rapid, convergent synthesis of diverse molecules and provide the foundation for modern chemical synthesis. The most widely used methods employ sp(2)-hybridized coupling partners, such as aryl halides or related pre-functionalized substrates. Here, we demonstrate coppe...
Autores principales: | Hu, Huayou, Chen, Si-Jie, Mandal, Mukunda, Pratik, Saied Md, Buss, Joshua A., Krska, Shane W., Cramer, Christopher J., Stahl, Shannon S. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7197765/ https://www.ncbi.nlm.nih.gov/pubmed/32368720 http://dx.doi.org/10.1038/s41929-020-0425-1 |
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