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Iridium Corroles Exhibit Weak Near-Infrared Phosphorescence but Efficiently Sensitize Singlet Oxygen Formation

Six-coordinate iridium(III) triarylcorrole derivatives, Ir[TpXPC)]L(2), where TpXPC = tris(para-X-phenyl)corrole (X = CF(3), H, Me, and OCH(3)) and L = pyridine (py), trimethylamine (tma), isoquinoline (isoq), 4-dimethylaminopyridine (dmap), and 4-picolinic acid (4pa), have been examined, with a vie...

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Detalles Bibliográficos
Autores principales: Thomassen, Ivar K., McCormick-McPherson, Laura J., Borisov, Sergey M., Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7200656/
https://www.ncbi.nlm.nih.gov/pubmed/32371925
http://dx.doi.org/10.1038/s41598-020-64389-3