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Exceptional Photochemical Stability of the Co–C Bond of Alkynyl Cobalamins, Potential Antivitamins B(12) and Core Elements of B(12)-Based Biological Vectors

[Image: see text] Alkynylcorrinoids are a class of organometallic B(12) derivatives, recently rediscovered for use as antivitamins B(12) and as core components of B(12)-based biological vectors. They feature exceptional photochemical and thermal stability of their characteristic extra-short Co–C bon...

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Detalles Bibliográficos
Autores principales: Salerno, Elvin V., Miller, Nicholas A., Konar, Arkaprabha, Salchner, Robert, Kieninger, Christoph, Wurst, Klaus, Spears, Kenneth G., Kräutler, Bernhard, Sension, Roseanne J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7201400/
https://www.ncbi.nlm.nih.gov/pubmed/32311266
http://dx.doi.org/10.1021/acs.inorgchem.0c00453