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Theoretical study on preference of open polymer vs. cyclic products in CO(2)/epoxide copolymerization with cobalt(III)-salen bifunctional catalysts
The preference of open chain of growing macromolecule vs. possible cyclic form was examined for the bifunctional cobalt(III)-salen catalyst for the copolymerization of CO(2) with epoxides. A variety of possible isomers was considered (resulting from trans/cis-β salen arrangement, different mutual or...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Berlin Heidelberg
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7203596/ https://www.ncbi.nlm.nih.gov/pubmed/32378131 http://dx.doi.org/10.1007/s00894-020-04364-x |