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Minimization of Amounts of Catalyst and Solvent in NHC-Catalyzed Benzoin Reactions of Solid Aldehydes: Mechanistic Consideration of Solid-to-Solid Conversion and Total Synthesis of Isodarparvinol B

[Image: see text] Attempts were made to minimize the amounts of catalyst and solvent in the NHC-catalyzed benzoin reactions of solid aldehydes. In some case, solid-to-solid conversions proceeded in the solvent-free NHC-catalyzed benzoin reactions. Even if a mixture of the substrate, N-heterocyclic c...

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Detalles Bibliográficos
Autores principales: Iwai, Kenta, Ono, Masakazu, Nanjo, Yoshiko, Ema, Tadashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7203951/
https://www.ncbi.nlm.nih.gov/pubmed/32391509
http://dx.doi.org/10.1021/acsomega.0c01141