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Selective Synthesis of N-Cyano Sulfilimines by Dearomatizing Stable Thionium Ions

[Image: see text] For the selective synthesis of N-cyano sulfilimines, we have developed a new method based on the soft–soft interaction between thionium ion electrophiles and cyanonitrene nucleophiles. The stable thionium ion was successfully obtained by oxidative dearomatization using phenyliodine...

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Detalles Bibliográficos
Autores principales: Kim, Sang Mee, Kang, On-Yu, Lim, Hwan Jung, Park, Seong Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7203956/
https://www.ncbi.nlm.nih.gov/pubmed/32391507
http://dx.doi.org/10.1021/acsomega.0c01086