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Bipyrrole boomerangs via Pd-mediated tandem cyclization–oxygenation. Controlling reaction selectivity and electronic properties

Boomerang-shaped bipyrroles containing donor–acceptor units were obtained through a tandem palladium-mediated reaction consisting of a cyclization step, involving double C–H bond activation, and a double α-oxygenation. The latter reaction can be partly suppressed for the least reactive systems, prov...

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Detalles Bibliográficos
Autores principales: Moshniaha, Liliia, Żyła-Karwowska, Marika, Cybińska, Joanna, Chmielewski, Piotr J, Favereau, Ludovic, Stępień, Marcin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7214875/
https://www.ncbi.nlm.nih.gov/pubmed/32461771
http://dx.doi.org/10.3762/bjoc.16.81