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Element–Element Bond Formation upon Oxidation and Reduction
The redox chemistry of [(Cp′′′Co)(2)(μ,η(2):η(2)‐E(2))(2)] (E=P (1), As (2); Cp′′′=1,2,4‐tri(tert‐butyl)cyclopentadienyl) was investigated. Both compounds can be oxidized and reduced twice. That way, the monocations [(Cp′′′Co)(2)(μ,η(4):η(4)‐E(4))][X] (E=P, X=BF(4) (3 a), [FAl] (3 b); E=As, X=BF(4)...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216884/ https://www.ncbi.nlm.nih.gov/pubmed/32017349 http://dx.doi.org/10.1002/anie.201916622 |