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Ligand Effects on the Electronic Structure of Heteroleptic Antimony‐Centered Radicals
We report on the structures of three unprecedented heteroleptic Sb‐centered radicals [L(Cl)Ga](R)Sb(.) (2‐R, R=B[N(Dip)CH](2) 2‐B, 2,6‐Mes(2)C(6)H(3) 2‐C, N(SiMe(3))Dip 2‐N) stabilized by one electropositive metal fragment [L(Cl)Ga] (L=HC[C(Me)N(Dip)](2), Dip=2,6‐i‐Pr(2)C(6)H(3)) and one bulky B‐ (2...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216903/ https://www.ncbi.nlm.nih.gov/pubmed/32048388 http://dx.doi.org/10.1002/anie.202000586 |