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Ligand Effects on the Electronic Structure of Heteroleptic Antimony‐Centered Radicals

We report on the structures of three unprecedented heteroleptic Sb‐centered radicals [L(Cl)Ga](R)Sb(.) (2‐R, R=B[N(Dip)CH](2) 2‐B, 2,6‐Mes(2)C(6)H(3) 2‐C, N(SiMe(3))Dip 2‐N) stabilized by one electropositive metal fragment [L(Cl)Ga] (L=HC[C(Me)N(Dip)](2), Dip=2,6‐i‐Pr(2)C(6)H(3)) and one bulky B‐ (2...

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Detalles Bibliográficos
Autores principales: Helling, Christoph, Cutsail, George E., Weinert, Hanns, Wölper, Christoph, Schulz, Stephan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216903/
https://www.ncbi.nlm.nih.gov/pubmed/32048388
http://dx.doi.org/10.1002/anie.202000586