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A Thioxanthone Sensitizer with a Chiral Phosphoric Acid Binding Site: Properties and Applications in Visible Light‐Mediated Cycloadditions

A chiral phosphoric acid with a 2,2’‐binaphthol core was prepared that displays two thioxanthone moieties at the 3,3’‐position as light‐harvesting antennas. Despite its relatively low triplet energy, the phosphoric acid was found to be an efficient catalyst for the enantioselective intermolecular [2...

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Detalles Bibliográficos
Autores principales: Pecho, Franziska, Zou, You‐Quan, Gramüller, Johannes, Mori, Tadashi, Huber, Stefan M., Bauer, Andreas, Gschwind, Ruth M., Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216904/
https://www.ncbi.nlm.nih.gov/pubmed/32065432
http://dx.doi.org/10.1002/chem.202000720