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Photoswitchable Norbornadiene–Quadricyclane Interconversion Mediated by Covalently Linked C(60)

The synthesis and properties of various norbornadiene/quadricyclane (NBD/QC) fullerene hybrids are reported. By cyclopropanation of C(60) with malonates carrying the NBD scaffold a small library of NBD–fullerene monoadducts and NBD–fullerene hexakisadducts was established. The substitution pattern o...

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Detalles Bibliográficos
Autores principales: Lorenz, Patrick, Hirsch, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216957/
https://www.ncbi.nlm.nih.gov/pubmed/31773822
http://dx.doi.org/10.1002/chem.201904679