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Sterically Demanding Ag(I) and Cu(I) N‐Heterocyclic Carbene Complexes: Synthesis, Structures, Steric Parameters, and Catalytic Activity

The synthesis and full characterization of new air‐stable Ag(I) and Cu(I) complexes bearing structurally bulky expanded‐ring N‐heterocyclic carbene (erNHC) ligands is presented. The condensation of protonated NHC salts with Ag(2)O afforded a collection of Ag(I) complexes, and their first use as liga...

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Detalles Bibliográficos
Autores principales: Cervantes‐Reyes, Alejandro, Rominger, Frank, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216994/
https://www.ncbi.nlm.nih.gov/pubmed/32104933
http://dx.doi.org/10.1002/chem.202000600