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Silicon‐Free SuFEx Reactions of Sulfonimidoyl Fluorides: Scope, Enantioselectivity, and Mechanism

SuFEx reactions, in which an S−F moiety reacts with a silyl‐protected phenol, have been developed as powerful click reactions. In the current paper we open up the potential of SuFEx reactions as enantioselective reactions, analyze the role of Si and outline the mechanism of this reaction. As a resul...

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Detalles Bibliográficos
Autores principales: Liang, Dong‐Dong, Streefkerk, Dieuwertje E., Jordaan, Daan, Wagemakers, Jorden, Baggerman, Jacob, Zuilhof, Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216998/
https://www.ncbi.nlm.nih.gov/pubmed/32157791
http://dx.doi.org/10.1002/anie.201915519