Cargando…
Silicon‐Free SuFEx Reactions of Sulfonimidoyl Fluorides: Scope, Enantioselectivity, and Mechanism
SuFEx reactions, in which an S−F moiety reacts with a silyl‐protected phenol, have been developed as powerful click reactions. In the current paper we open up the potential of SuFEx reactions as enantioselective reactions, analyze the role of Si and outline the mechanism of this reaction. As a resul...
Autores principales: | Liang, Dong‐Dong, Streefkerk, Dieuwertje E., Jordaan, Daan, Wagemakers, Jorden, Baggerman, Jacob, Zuilhof, Han |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7216998/ https://www.ncbi.nlm.nih.gov/pubmed/32157791 http://dx.doi.org/10.1002/anie.201915519 |
Ejemplares similares
-
Synthesis of Highly Enantioenriched Sulfonimidoyl Fluorides and Sulfonimidamides by Stereospecific Sulfur–Fluorine Exchange (SuFEx) Reaction
por: Greed, Stephanie, et al.
Publicado: (2020) -
Sulfur–Phenolate Exchange: SuFEx‐Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
por: Chao, Yang, et al.
Publicado: (2022) -
Configurationally Chiral SuFEx‐Based Polymers
por: Liang, Dong‐Dong, et al.
Publicado: (2022) -
Quantitative and Orthogonal Formation and Reactivity of SuFEx Platforms
por: Gahtory, Digvijay, et al.
Publicado: (2018) -
Nickel-Catalyzed Suzuki Coupling of Phenols Enabled by SuFEx of Tosyl Fluoride
por: Wang, Huimin, et al.
Publicado: (2023)