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Mercury‐Free Synthesis of Pincer [C^N^C]Au(III) Complexes by an Oxidative Addition/CH Activation Cascade

Starting from the commercially available dimethyl sulfide‐gold(I) chloride complex (DMSAuCl) and diazonium salts in the presence of 2,6‐di‐tert‐butyl‐4‐methylpyridine as base, symmetric and unsymmetric [C^N^C]Au(III)Cl complexes were synthesized in a selective, photosensitizer‐free, photochemical re...

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Detalles Bibliográficos
Autores principales: Eppel, Daniel, Rudolph, Matthias, Rominger, Frank, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7217051/
https://www.ncbi.nlm.nih.gov/pubmed/32134179
http://dx.doi.org/10.1002/cssc.202000310