Transient-axial-chirality controlled asymmetric rhodium-carbene C(sp(2))-H functionalization for the synthesis of chiral fluorenes

In catalytic asymmetric reactions, the formation of chiral molecules generally relies on a direct chirality transfer (point or axial chirality) from a chiral catalyst to products in the stereo-determining step. Herein, we disclose a transient-axial-chirality transfer strategy to achieve asymmetric r...

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Detalles Bibliográficos
Autores principales: Dong, Kuiyong, Fan, Xing, Pei, Chao, Zheng, Yang, Chang, Sailan, Cai, Ju, Qiu, Lihua, Yu, Zhi-Xiang, Xu, Xinfang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7217916/
https://www.ncbi.nlm.nih.gov/pubmed/32398762
http://dx.doi.org/10.1038/s41467-020-16098-8

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7217916/
https://www.ncbi.nlm.nih.gov/pubmed/32398762
http://dx.doi.org/10.1038/s41467-020-16098-8

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