Cargando…
Transient-axial-chirality controlled asymmetric rhodium-carbene C(sp(2))-H functionalization for the synthesis of chiral fluorenes
In catalytic asymmetric reactions, the formation of chiral molecules generally relies on a direct chirality transfer (point or axial chirality) from a chiral catalyst to products in the stereo-determining step. Herein, we disclose a transient-axial-chirality transfer strategy to achieve asymmetric r...
| Autores principales: | , , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7217916/ https://www.ncbi.nlm.nih.gov/pubmed/32398762 http://dx.doi.org/10.1038/s41467-020-16098-8 |