Easy Ligand Activation in the Coordination Sphere of Ru inside the [PW(11)O(39)](7–) Backbone

Irradiation of the Keggin-type [PW(11)O(39){Ru(NO)}](4−) (Ru-NO) polyoxometalate in CH(3)CN results in rapid NO ligand elimination with the formation of [PW(11)O(39){Ru(III)(CH(3)CN)}](4−) (Ru-CH(3)CN). This complex offers an easy entry into the Ru-based chemistry of the {PW(11)Ru} complex. Attempts...

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Detalles Bibliográficos
Autores principales: Mukhacheva, Anna A., Gushchin, Artem L., Yanshole, Vadim V., Abramov, Pavel A., Sokolov, Maksim N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7221517/
https://www.ncbi.nlm.nih.gov/pubmed/32316614
http://dx.doi.org/10.3390/molecules25081859

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7221517/
https://www.ncbi.nlm.nih.gov/pubmed/32316614
http://dx.doi.org/10.3390/molecules25081859

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