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Experimental and Computational Studies Unraveling the Peculiarity of Enolizable Oxoesters in the Organocatalyzed Mannich-Type Addition to Cyclic N-Acyl Iminium Ions

γ− and δ-Oxoesters are easily available starting materials that have been sparingly used in some organocatalyzed reactions proceeding with a high enantioselectivity. In our experimentation we found that the use of these compounds as the enolizable (nucleophilic) component in organocatalyzed Mannich-...

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Detalles Bibliográficos
Autores principales: Menichetti, Andrea, Di Pietro, Sebastiano, Di Bussolo, Valeria, Favero, Lucilla, Pineschi, Mauro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7221655/
https://www.ncbi.nlm.nih.gov/pubmed/32326095
http://dx.doi.org/10.3390/molecules25081903