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Experimental and Computational Studies Unraveling the Peculiarity of Enolizable Oxoesters in the Organocatalyzed Mannich-Type Addition to Cyclic N-Acyl Iminium Ions
γ− and δ-Oxoesters are easily available starting materials that have been sparingly used in some organocatalyzed reactions proceeding with a high enantioselectivity. In our experimentation we found that the use of these compounds as the enolizable (nucleophilic) component in organocatalyzed Mannich-...
Autores principales: | Menichetti, Andrea, Di Pietro, Sebastiano, Di Bussolo, Valeria, Favero, Lucilla, Pineschi, Mauro |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7221655/ https://www.ncbi.nlm.nih.gov/pubmed/32326095 http://dx.doi.org/10.3390/molecules25081903 |
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